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ARTÍCULO
TITULO

Platform Molecule Removal from Aqueous Mixture with Organophilic Pervaporation: Experiments and Modelling

Eniko Haáz    
Nóra Valentinyi    
Ariella Janka Tarjani    
Daniel Fózer    
Anita André    
Selim Asmaa Khaled Mohamed    
Fuad Rahimli    
Tibor Nagy    
Péter Mizsey    
Csaba Deák    
András József Tóth    

Resumen

The work is motivated by a separation problem, which is ethanol removal from aqueous mixtures with membranes. Ethanol can be considered as promising biomass based platform molecule. The platform molecule includes several building-block chemicals grouped together, resulting in a range of downstream chemical products. To solve the target, organophilic pervaporation system is investigated using benchmarked Sulzer PERVAP? 4060 membranes. Separation factors, total permeation fluxes, permeances and selectivities are experimentally determined. The target of this work is to parameter estimation for semi-empirical pervaporation model. The measured data are evaluated with improved pervaporation model by Valentinyi et al. [1]. Three different polymeric flat sheet membranes are investigated, PERVAP? 4060, PERVAP? 1060 and CELFA-CMG-OG010. It is found that the model can be applied also for each organophilic separation case.

PÁGINAS
pp. 138 - 146
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